Williams could refer to:
- Williams (Commander), of Earth Starfleet
- Williams (Female Ensign), a Starfleet tactical ensign
- Williams (Male Ensign), a Starfleet ensign studying art
- Bernie Williams (Starfleet), of Fleet Operations
- Clarence Williams III, Omet'iklan from the DS9 episode "To The Death".
- Cress Williams, Talak'talan from the DS9 episode "The Jem'Hadar".
- Justin Williams, Crewman Jarvin from Star Trek: Voyager.
- Spice Williams, Vixis from Star Trek V: The Final Frontier and a stuntperson.
- Vanessa Williams, Arandis from the DS9 episode "Let He Who Is Without Sin".
- Anson Williams, director of several episodes.
- Bernie Williams, executive producer on Star Trek Generations.
- Williams (dga trainee), a dga trainee on The Next Generation.