Williams could refer to:
- Williams (Commander), of Earth Starfleet
- Williams (Female Ensign), a Starfleet tactical ensign
- Williams (Male Ensign), a Starfleet ensign studying art
- Bernie Williams (Starfleet), of Fleet Operations
- Clarence Williams III, Omet'iklan from the DS9 episode "To The Death"
- Cress Williams, Talak'talan from the DS9 episode "The Jem'Hadar"
- Harry Williams, Jr., a background actor on The Next Generation and Generations
- Justin Williams, Crewman Jarvin from Star Trek: Voyager
- Spice Williams, Vixis from Star Trek V: The Final Frontier and a stuntperson
- Vanessa Williams, Arandis from the DS9 episode "Let He Who Is Without Sin"
- Production staff
- Anson Williams, director of several episodes
- Bernie Williams, executive producer on Star Trek Generations
- Williams (dga trainee), a dga trainee on The Next Generation
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