Volchok Prime was the inhabited prime planet in its system.

In 2369, the influential Ferengi Hoex bought out his rival Turot's controlling interest in the cargo ports on Volchok Prime. (DS9: "The Nagus")

This planet was only mentioned in dialogue.
According to Star Trek: Star Charts ("United Federation of Planets I") and Stellar Cartography: The Starfleet Reference Library ("Federation Historical Highlights, 2161-2385"), the Volchok system was located in the Alpha Quadrant. The system's primary was a F-class star. In the late 24th century, it was an independent system.

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