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In 2151, Captain Jonathan Archer offered Tolaris coffee from a thermos in the captain's ready room, prior to Tolaris leaving Enterprise NX-01 aboard the Vulcan civilian transport Vahklas. (ENT: "Fusion")
At one point on Orpheus Mining colony in 2155, John Frederick Paxton offered Charles Tucker III a drink from a thermos. However, Tucker refused the beverage, so Paxton drank it himself. (ENT: "Terra Prime")