In 2293, the location of Rigel in the Milky Way Galaxy was labeled in a star chart that was in Captain James T. Kirk's quarters aboard the USS Enterprise-A. (Star Trek VI: The Undiscovered Country, production art)
In 2366, in an alternate timeline, during the Federation-Klingon War, the location of Rigel was labeled on a tactical situation monitor in the ready room aboard the USS Enterprise-D (TNG: "Yesterday's Enterprise", display graphic)
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In early 2155, the Rigelians participated in talks discussing their wish to join as a possible member in the Coalition of Planets along with Humans, Tellarites, Andorians, Coridans and Vulcans. (ENT: "Demons", "Terra Prime")
Rationale: Rigel V was only mentioned in a single episode, so why are four episodes cited? All the above has been removed for not pertaining to the planet itself -- Capricorn (talk) 14:43, August 18, 2016 (UTC)
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Rigel V is mentioned in the Magnetic Fields song Judy Garland off of their 50 Song Memoir album.