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Quark didn't think too highly of the Bajoran variety of synthale, calling it "dreadful". When Benjamin Sisko asked him about the local synthale, he remarked "Never trust ale from a god-fearing people." (DS9: "Emissary")
One variety of synthale was called Voodai. It was Major Kira's favorite synthale. Quark gave her a bottle as a farewell present in early 2370, after she had previously remarked jokingly that her friends could help her "cry in her synthale". (DS9: "The Circle")
Quark remarked to Arjin, that Julian Bashir was sitting in his bar every other day, "crying in his synthale" about Jadzia Dax. Similarly, Arjin tried to forget his worries with a large bottle of synthale, pretending to "see his future" in a full glass of the drink. Dax commented that she wouldn't trust a bottle of synthale to tell the future. (DS9: "Playing God")
In a simulation created by the Founders, Bashir and Miles O'Brien ordered two synthales. Quark told them, the drinks were on the house, as he was in a good mood, having heard that a peace agreement with the Dominion would soon be reached. (DS9: "The Search, Part II")
After getting drunk on a large bottle of whiskey and singing Jerusalem, Chief O'Brien contemplated switching to synthale for a moment, but Doctor Bashir replied that it wasn't a "synthale-kind of night". (DS9: "Explorers")
O'Brien liked his synthale extra-stout. When he was engaging in a darts-competition with the Vulcan Syvar, O'Brien severely injured his right shoulder when Quark handed him the drink. (DS9: "Shakaar")
After the Bajoran Time of Cleansing of the same year was over, Major Kira ordered two mugs of synthale and a double order of hasperat for herself and a fellow Bajoran officer. (DS9: "Bar Association")
After returning from imprisonment by the Argrathi, Miles O'Brien ordered a synthale in Quark's and threatened the barkeeper that he would "break every bone" in his "worthless little body" when Quark took longer than usual to give the chief his drink. (DS9: "Hard Time")