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On Earth, during the 13th century, Humans were still perfecting the mechanical clock and using steel crossbows in battle at the time the Promellians were building interstellar warships. (TNG: "Booby Trap")
The emergency baffles used in the ventaliation system at the facility on the trellium mining planet were steel plates. These plates would be locked into place during maintenance cycles. (ENT: "The Xindi")
The level of metallurgic technology achieved by the species who inhabited the class L planet, in the Delta Quadrant, that B'Elanna Torres crashed on in 2376 were not yet able to produce steel, as they were still at the bronze level of development. (VOY: "Muse")
Dukat complimented Kira Nerys by stating that she was "the embodiment of the new Bajor-- a Bajoran born out of the ashes of the occupation. A Bajoran tempered with Cardassian steel." (DS9: "Indiscretion")