"Spell of the Spider" was Chapter 16 in Tom Paris' The Adventures of Captain Proton holonovel.
It depicted Queen Arachnia sending Doctor Chaotica a vial of irresistible pheromones, which caused him to fall under her spell whenever he smelled them. The vial was situated on a small pedestal next to Chaotica's throne in the Fortress of Doom on Planet X. (VOY: "Bride of Chaotica!")
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