Sin was a term used to describe certain acts considered to be bad. A person who sinned was called a sinner.
In 2266, discipline broke down aboard the USS Enterprise as a result of polywater intoxication. Among the resulting incidents were graffiti appearing saying "sinner repent". (TOS: "The Naked Time")
Tam Elbrun told Data that being different was not a sin, though he thought the android may have heard otherwise. (TNG: "Tin Man")
When The Doctor role-played as Father Mulligan in the holoprogram Paris 042, he often labeled people sinners. (VOY: "Fair Haven", "Spirit Folk")
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