Silver is an element, atomic number 47 on the periodic table. (TOS: "The Naked Time") Silver was used to make Olympic medals. (ENT: "Cold Station 12")

While temporarily residing in 1930 New York City, James T. Kirk assured Spock that he would be unable to acquire precious metals such as gold, silver, or platinum for Spock's mnemonic memory circuit. (TOS: "The City on the Edge of Forever")

In 2366, while on the planet Galorndon Core, Geordi La Forge melted chunks of silver ore with his hand phaser, fashioned them into a pair of spikes, and used them to make a difficult climb out of a pit. (TNG: "The Enemy")

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