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In 2267, the ornithoid lifeforms from outside the Milky Way Galaxy, Sylvia and Korob, established an outpost there for the purpose of learning about the worlds of the Federation. Sylvia became infatuated with sensation, and dangerously irrational. To stop her, James T. Kirk destroyed the transmuter used by the aliens. Without its power, the two aliens were not able to survive on the surface of Pyris VII and died. (TOS: "Catspaw")
In 2293, the location of Pyris VII in the Milky Way Galaxy was labeled in a star chart that was in Captain James T. Kirk's quarters aboard the USS Enterprise-A. (Star Trek VI: The Undiscovered Country, okudagram)