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In 2375, Species 8472 utilized particle synthesis in combination with holographic projections to recreate Starfleet Headquarters in their terraspheres, with which to train operatives to infiltrate Starfleet. (VOY: "In the Flesh")
According to the Pocket Books novel Greater than the Sum, particle synthesis is related to the Quantum Slipstream technology. In the novel, it is explained that the particle synthesis works by exploiting, and altering, virtual particles on a quantum level.