Chancellor M'Rek was chancellor of the Klingon High Council in the mid-22nd century, who ascended to the position sometime after 2151. Rumors had been going around that he was fond of Orion slave girls.

While in pursuit of a Klingon Bird-of-Prey hijacked by Augments, Enterprise NX-01, disguised with a Klingon warp field, was contacted by a Klingon battle cruiser. Captain Jonathan Archer fooled the commander into withdrawing by claiming that he was transporting Chancellor M'Rek back to Qo'noS from negotiations with the Orions. (ENT: "The Augments")

This character was only mentioned in dialogue.
This might be the same unnamed chancellor seen one year earlier in "The Expanse".

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