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Gasoline was a form of liquid fuel created from refined petroleum. It is made up of complex hydrocarbons including benzene, ethylene and acetylene. During the 20th and 21st century it was used to drive internal combustion engines in Earth vehicles until the latter half of the 21st century. (VOY: "The 37's", ENT: "Carpenter Street")
When Captain Archer and T'Pol time traveled back to 2004, they borrowed a parked Dodge Ram and realized it needed gasoline when an icon blinked on the dashboard, reminding them that they'd need currency in that time period. (ENT: "Carpenter Street")
In 2153, after Enterprise's antimatter supply had been stolen by Osaarian pirates, Trip Tucker said that in a month at most they would be "out of gas" when the warp reactor's supply had been exhausted. (ENT: "Anomaly")
During the USS Excelsior's encounter with Kang's battle cruiser in 2293 in the Azure Nebula, it was suggested by Tuvok that the ship could emit a modulated positron beam to a subspace frequency to trigger a thermochemical reaction in the nebula's sirillium to fashion an escape. Captain Sulu, who was keen on the suggestion, likened it to "tossing a match into a pool of gasoline." (VOY: "Flashback")