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(covers information from an alternate timeline)
In 2154, Klingon Doctor Antaak gave a flask to Denobulan Doctor Phlox while the latter was enduring imprisonment in Qu'Vat colony. However, Phlox chose not to drink from the flask. (ENT: "Divergence")
Phlox's captor, General K'Vagh, had a flask of his own, which was filled with alcohol. At one point, he used it to toast the bravery of two Klingon warriors under his command. Phlox also declined to drink from this flask. (ENT: "Divergence")