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A dart was a small projectile. Pointed at one end, they could be tipped with poison or a tranquilizer. (TOS: "Where No Man Has Gone Before", VOY: "Distant Origin") They were also used in the game of darts. (DS9: "Prophet Motive" et al.)
A rodent-like species that lived on the planet Dimorus used poison darts as a weapon. Sometime prior to 2265, Gary Mitchell took one meant for James T. Kirk and almost died. Mitchell recalled the incident after developing heightened powers due to exposure to the galactic barrier. (TOS: "Where No Man Has Gone Before")
The Voth used dart-firing weapons. In 2373, the Voth shot Chakotay and Tuvok with tranquilizer darts, eventually taking Chakotay alive so they could have a living specimen in order to study and confirm the Distant Origin Theory. (VOY: "Distant Origin")