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In 2153, Jonathan Archer exchanged several spices from Enterprise's galley, including cayenne pepper, mustard seed, paprika, and pepper in exchange for the formula necessary for synthesizing trellium. (ENT: "Rajiin")
Cayenne pepper was a popular seasoning among various members of the Sisko family. However, Joseph Sisko felt that his daughter Judith never put enough cayenne pepper in jambalaya. (DS9: "Homefront", "Accession")