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Boridium power cells were used in the construction of Romulan mines which the Enterprise NX-01 encountered in 2152. In 2154, the Romulans utilized a similar technology in the power matrices of their drone ships, although they were smaller and much more sophisticated. (ENT: "Minefield", "Babel One")
The Hill People of the Argus River region on Rigel IV used boridium for the blades of a kind of knife they produced; one such weapon was involved in a series of murders on Argelius II in 2267. (TOS: "Wolf in the Fold")