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Pepper was a seasoning that often went alongside salt. In cooking, pepper was usually added to a recipe in quantities referred to as "to taste." Gideon Seyetik used pepper in his recipe for stew which he cooked for the senior staff of Deep Space 9 in 2370. (DS9: "Second Sight")
In 2153, Jonathan Archer exchanged several spices from the Enterprise's galley, including cayenne pepper, mustard seed, paprika, and pepper, in exchange for the formula necessary for synthesizing trellium. (ENT: "Rajiin")